Many-Body Theory for Hyperfine Fields in Iron-Group Ions—Ferric Ion

1 December 1973

journal article
research article
Published by American Physical Society (APS) in Physical Review B

Vol. 8 (11) , 5291-5297
https://doi.org/10.1103/physrevb.8.5291

Abstract

The hyperfine constant of

{Fe}^{+ 3}

ion is calculated by the linked-cluster many-body theory procedure. The first-order contribution representing exchange-core-polarization (ECP) effect leads to a hyperfine constant of - 45.46 MHz. Electron-electron interaction effects involving both consistency and correlation contribution are found to be about 12% of the ECP effect. Comparison is made with experimental hyperfine fields in solid state from Mössbauer studies, and the relative importance of covalency effects as compared to electron-electron interaction effects on the hyperfine constant are discussed.

Keywords

This publication has 21 references indexed in Scilit:

Many-Body Theory of the Magnetic Hyperfine Interaction in the Excited State ( $1 s^{2} 2 s 2 p {}^{3}P$ ) of the Beryllium Atom
Physical Review A, 1973
Measurement of $2 s$ and $3 s$ Electron Spin Density in Iron Metal
Physical Review Letters, 1972
Multiplet Splitting of the $4 s$ and $5 s$ Electrons of the Rare Earths
Physical Review B, 1972
Hyperfine Structure of Sodium
Physical Review A, 1970
Many-Body Approach to Hyperfine Interaction in Atomic Nitrogen
Physical Review B, 1969
Brueckner-Goldstone Many-Body Theory for the Hyperfine Structure of Phosphorus
Physical Review Letters, 1968
Many-Body Approach to the Atomic Hyperfine Problem. I. Lithium-Atom Ground State
Physical Review B, 1968
Hyperfine Contact Interactions in Oxygen Calculated by Many-Body Theory
Physical Review B, 1968
Mößbauereffekt in Eisenstilben und FeCl2·H2O
The European Physical Journal A, 1968
Hyperfine Interactions and the Magnetic Fields Due to Core Polarization in ${Fe}^{57}$
Physical Review B, 1966