Crystal structure and pressure dependence of electrical conductivities of [(CH3)4N][Pt(dmit)2]2
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 1 (5) , 827-830
- https://doi.org/10.1039/jm9910100827
Abstract
The crystal structure and electrical conductivities (including the effect of pressure) of [(CH3)4N][Pt(dmit)2]2(dmit = 4,5-dimercapto-1,3-dithiole-2-thione) have been studied. The Pt(dmit)2 anions form dimeric structures arranged as one-dimensional stacks along the [110] and [10] directions. A simple band-energy calculation indicates that the conduction band is formed by the HOMO band of Pt(dmit)2 owing to the strong dimeric nature of the molecular stacks.Keywords
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