Chiral (Acyloxy)borane Catalyzed Asymmetric Allylation of Aldehydes
- 1 January 1991
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1991 (08) , 561-562
- https://doi.org/10.1055/s-1991-20797
Abstract
Chiral (acyloxy)borane, obtained from (2R, 3R)-2-O-(2,6-diisopropoxybenzoyl)tartaric acid and tetrahydrofuranborane complex, catalyzes the allylation of achiral aldehydes with allylsilanes to afford homoallylic alcohols with high enantiomeric excess. The reactions proceed in a catalytic manner.Keywords
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