1D porous framework of copper(ii) showing a novel coordination mode of Ni(CN)42−

Abstract
A novel porous framework [{Cu2(medpt)2Ni(CN)4}(ClO4 )2· 2.5H2O]n 1, [medpt = bis(3-aminopropyl)methylamine] is prepared where all the CN groups of Ni(CN)4 2− are involved in bridging; this material retains single crystallinity upon removal of water guest molecules and the dehydrated species 2 selectively binds organic molecules.
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