Non-bonded vs. bonded interactions in (Ph3P)4Ag2Br2–(Ph3P)4Ag4Br4and its stereochemical analogue [(RS)4Fe2S2]2––[(RS)4Fe4S4]2–
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 185-186
- https://doi.org/10.1039/c39760000185
Abstract
The stereochemistry of the metal-metal non-bonded dimer-tetramer pair (Ph3P)4Ag2Br2–(Ph3P)4Ag4Br4 exhibits trends resembling those of the structurally analogous metal-metal bonded pair [(RS)4Fe2S2]2––[(RS)4 S4]2–, indicating that the metal atoms within each pair probably bear similar gross atomic charges.Keywords
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