Radiation-induced oxidation and reduction of iron–cyanide complexes
- 1 March 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (5) , 2135-2138
- https://doi.org/10.1063/1.434177
Abstract
The species [Fe(CN)6]3− was generated by ionizing radiation in single crystals of Na4Fe(CN)6⋅10H2O maintained at 4.2°K. Three different conformations of the complex were obtained giving g tensors whose principal values are the following: 2.68, 2.53, 1.19; 2.74, 2.43, 0.63, and 2.81, 2.28, 1.45. Reduction products are formed in which the unpaired electron occupies an antibonding molecular orbital formed from iron and ligand orbitals.Keywords
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