Regulation of equilibria in the catalytic asymmetric allylic transfer reaction: unusual 1,2-carbonyl addition of 3-trimethylsilyl-2-propenylstannaneElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b304356h/
- 18 June 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 14,p. 1744-1745
- https://doi.org/10.1039/b304356h
Abstract
Catalytic enantioselective addition of 3-trimethylsilyl-2-propenylstannane to aldehydes promoted by BINOL–Ti(IV) catalyst along with synergistic reagent provides unusual 1,2-adducts with high levels of enantioselectivity.Keywords
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