The crystal and molecular structure of dimethyl-π-cyclopentadienyl(methylcyclopentadiene)rhenium
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2001-2009
- https://doi.org/10.1039/j19670002001
Abstract
The crystal structure of dimethyl-π-cyclopentadienyl(methylcyclopentadiene)rhenium, C5H5Re(CH3)2·C5H5·CH3 has been determined by single-crystal X-ray diffraction, by use of the heavy-atom method. The rings are inclined at an angle of 45° with two methyl groups lying in the plane bisecting this angle. The methylcyclopentadiene ring is non-planar. The mean Re–C bond distance is 2·24 Å. The crystals are monoclinic, space-group P21/c, a= 12·588, b= 7·751, c= 14·347 Å, β= 122·92°.Keywords
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