Notizen: Substitution of CO for CN— in Cyclopentadienyl Carbonyl Vanadium Compounds
Open Access
- 1 February 1976
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 31 (2) , 273-274
- https://doi.org/10.1515/znb-1976-0228
Abstract
UV irradiation of [Me4N][VCp(CO)3] and [Me4N]CN results in the formation of a complex with zero-valent vanadium which possibly has to be formulated as [Me4N]4[CpV(CO)2CN]2. A new method of preparation of K[CpV(CO)3CN] is described; 51V NMR results and a complete IR spectrum are presented and discussed.Keywords
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