One-pot synthetic route to homoallylketones via selective combination of alkyne, ethylene and aldehyde mediated by AlCl3 and zirconoceneElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b1/b109761j/
- 9 January 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 2,p. 142-143
- https://doi.org/10.1039/b109761j
Abstract
Zirconacyclopentenes generated in situ from alkynes and ethylene undergo selective reaction with aldehydes to afford homoallylketones in yields exceeding 70% in the presence of AlCl3.Keywords
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