A rapid and effective synthesis of propylene carbonate using a supercritical CO2–ionic liquid system
Top Cited Papers
- 7 March 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 896-897
- https://doi.org/10.1039/b212823c
Abstract
The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than those so far reported.Keywords
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