Perkin communications. Diastereoselective alkylation of ketone enolates using a 1,3-dithiane 1-oxide auxiliary
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 1,p. 185-187
- https://doi.org/10.1039/p19890000185
Abstract
Acyldithiane 1-oxides readily undergo deprotonation to give chelated metal enolates which react with iodomethane to give alkylated products with good selectivity.Keywords
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