Variable temperature 13C nuclear magnetic resonance of dicyclopentadienyltricarbonyldirhodium
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 79-80
- https://doi.org/10.1039/c39730000079
Abstract
The 13C n.m.r. chemical shifts of bridging and terminal carbonyl carbons in (π-C5H5)2Rh2(CO)3 have been established from 103Rh–13C coupling data at –80°; at 20° the spectrum shows rapid intramolecular interconversion of all carbonyl groups.Keywords
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