Polyhedral Clathrate Hydrates. X. Structure of the Double Hydrate of Tetrahydrofuran and Hydrogen Sulfide
- 15 April 1965
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 42 (8) , 2732-2737
- https://doi.org/10.1063/1.1703229
Abstract
The structure of the tetrahydrofuran/hydrogen sulfide double hydrate has been determined from three‐dimensional single‐crystal data. The analysis confirmed the clathrate host lattice characteristic of 17‐Å cubic (Type II) gas hydrates. The hexakaidecahedral voids enclose tetrahydrofuran molecules which appear to undergo free rotation. Statistically, 46% of the pentagonal dodecahedra are occupied by hydrogen sulfide molecules.Keywords
This publication has 12 references indexed in Scilit:
- Ozone - Carbon Tetrachloride Double HydrateNature, 1964
- Clathrate Hydrates of Soluble Non-electrolytesNature, 1964
- Cold Box for Use with a Weissenberg X-Ray Diffraction CameraReview of Scientific Instruments, 1963
- ICE VIII—AN ACETONE HYDRATE?The Journal of Physical Chemistry, 1961
- New Clathrate Compounds of the Inert GasesNature, 1960
- The Conformations of Substituted Cyclopentanes. I. The Infrared Analysis and Structure of the α-Halocamphors, the α-Halo-2-indanones and the α-HalocyclopentanonesJournal of the American Chemical Society, 1959
- On the Structure of Gas HydratesThe Journal of Chemical Physics, 1951
- Suggested Structures of Water in Inert Gas HydratesThe Journal of Chemical Physics, 1951
- Neutron Diffraction Study of the Structure of IcePhysical Review B, 1949
- The Rotational Motion of Molecules in CrystalsPhysical Review B, 1930