The Oxygen Exchange Reaction of Phenol in Acidic Media
- 1 September 1966
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 39 (9) , 1961-1967
- https://doi.org/10.1246/bcsj.39.1961
Abstract
The acid-catalyzed oxygen exchange reaction to a number of phenolic compounds that is, phenol, o- m- and p-hydroxy phenols, α- and β-naphthols, o- m- and p-nitrophenols, o- m- and p-aminophenols, o- and p-bromophenols, 2, 4, 6-tribromophenol, o- m- and p-cresols and 2, 4, 6-trimethylphenol, plus quinone for comparison with 18O-enriched water was carried out under various conditions. A plot of the logkx⁄kh line against Hammett σ-constants in the substituted phenols gave a fairly good correlation line (ρ=0.47) except in the cases of p-bromophenol and p-aminophenol. The mechanism of these reactions has been discussed.This publication has 10 references indexed in Scilit:
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