Direct Oxidation of Liquid Fuels in a Solid Oxide Fuel Cell

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Abstract
We report stable power generation, ∼0.1W/cm2,∼0.1W/cm2, from the direct electrochemical oxidation, without reforming, of toluene, nn -decane, and synthetic diesel fuel at 973 K in a solid oxide fuel cell with a composite anode containing Cu and ceria. The liquid fuels were injected directly into the anode compartment and the performance for each fuel with 50% N2N2 dilution was stable for a period of at least 12 h. Photographs of Cu-yttria-stabilized zirconia (YSZ) and Ni-YSZ composites exposed to 50% toluene in N2N2 at 973 K for 1.5 h showed little carbon formation on the Cu-YSZ but demonstrated that the Ni-YSZ was covered with carbon and fractured by this environment. © 2001 The Electrochemical Society. All rights reserved.