Oxidative addition of methyl lodide to dicarbonylrhodium(I) complexes
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1609-1611
- https://doi.org/10.1039/c39840001609
Abstract
Oxidative addition of Mel to [Rh(CO)2l2]– in aprotic solvents, the ‘rate-determining’ step in the carbonylation of methyl acetate and methyl halides(to acetic anhydride and acyl halides, respectively), is substantially promoted by iodide and bases (L, e.g. 1-methylimidazole).Keywords
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