Delayed Nucleation at a Weakly First-Order Transition

Abstract
The dynamics of the transformation out of a nonequilibrium metastable phase is discussed within a mean-field theory at temperatures below the transition temperature Tc. We show that fluctuations are important and lead to an unusual time dependence of the order parameter, in particular a sharp delay time for the onset of the stable phase. This model is applied to the dynamics of the paraelectric to ferroelectric transition in BaTiO3 where the mediating forces arise from long-range strain fields.