Synthesis, Structure, and Electrochemical Properties of New “Unsymmetrical” Metal Dithiolate Complexes
- 1 September 1997
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 26 (9) , 921-922
- https://doi.org/10.1246/cl.1997.921
Abstract
New “unsymmetrical” (mixed ligand) metal dithiolate complexes, expected as components of molecular conductors, have been obtained by a ligand-exchange reaction in refluxing acetone, followed by isolation with a preparative HPLC (ODP; acetonitrile-H2O). Their electrochemical data suggest that the acceptor (donor) ability and the on-site Coulomb energy for the “unsymmetrical” complexes can be tuned by a combination of ligands.Keywords
This publication has 7 references indexed in Scilit:
- Molecular metals and superconductors derived from metal complexes of 1,3-dithiol-2-thione-4,5-dithiolate (dmit)Coordination Chemistry Reviews, 1991
- Synthesis and properties of bis(ethylenedithio)tetraselenafulvalene (BEDT-TSeF) compoundsSynthetic Metals, 1991
- Crystal structures of bis(5,6-dihydro-1,4-dithiin-2,3-dithiolato)gold and tetrabutylammonium bis(5,6-dihydro-1,4-dithiin-2,3-dithiolato)nickelate(1-) and the ligandlike character of the isoelectronic radicals [Au(DDDT)2]0 and [Ni(DDDT)2]-Inorganic Chemistry, 1987
- Preparation, structure and properties of [Ni(S2C2(CN)2)2]− salts with small cationsSynthetic Metals, 1987
- Coordination chemistry of new sulfur containing ligands. 27. Synthesis and coordination chemistry of a new 1,2-dithiolene containing the tetrathioethylene unitInorganic Chemistry, 1985
- Ligand exchange reactions between copper(II)- and nickel(II)-chelates of different sulfur- and selenium-containing ligands—IIJournal of Inorganic and Nuclear Chemistry, 1980
- Ligand-Exchange Reactions of Bis(cis-1,2-disubstituted ethylene-1,2-dithiolato)nickel ComplexesJournal of the American Chemical Society, 1967