Synthesis of Nitro-trimethylsilyl-acetylene
- 1 January 1986
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1986 (02) , 132-133
- https://doi.org/10.1055/s-1986-31496
Abstract
A practical, one step, high yield synthesis of nitro-trimethylsilyl-acetylene (1), by treating bis[trimethylsilyl]acetylene with nitronium tetrafluoroborate in dichloromethane is described. Compound 1 was also obtained (in low yield) when bis-trimethylsilylacetylene was treated with nitryl fluoride in dichloromethane; the major reaction products resulted from addition of nitryl fluoride across the triple bond.Keywords
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