Photoelectron (He I) spectroscopic study of styrylpyridines
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 71, 1583-1589
- https://doi.org/10.1039/f29757101583
Abstract
The He I photoelectron spectra of the three isomeric trans-styrylpyridines and some of their derivatives are reported. The assignments were made with the aid of CNDO/S calculations coupled with perturbational molecular orbital analysis, and substituent effects were compared with available data on benzenes and stilbenes. The possible correlation of these results with the electronic spectra and photochemical behaviour of azastilbenes is briefly discussed.Keywords
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