Nanoclusters in Ionic Liquids: Evidence for N-Heterocyclic Carbene Formation from Imidazolium-Based Ionic Liquids Detected by 2H NMR
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- 1 April 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (16) , 5758-5759
- https://doi.org/10.1021/ja0423320
Abstract
The mystery of how 1,3-substituted imidazolium-based ionic liquids (ILs) can provide high stabilization for transition-metal(0) nanoclusters, that is, in the absence of the usual strongly coordinating anions, has been probed. 2H NMR product and kinetic studies of 1,3-substituted imidazolium ILs under D2 reveal that nanocluster-catalyzed H/D exchange occurs at the 2- (as well as at the 4-, 5-, and 8-) C−H positions of the imidazolium cation. The results (i) provide compelling evidence that N-heterocyclic carbene formation and ligation of nanoclusters is occurring in ILs; and (ii) argue that N-heterocyclic carbenes merit further investigation as heretofore unappreciated stabilizers of transition-metal nanoclusters.Keywords
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