LYCOCTONINE AND ITS OXIDATION PRODUCTS
- 1 September 1952
- journal article
- research article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 30 (9) , 627-645
- https://doi.org/10.1139/v52-075
Abstract
The ultraviolet spectra, basic strengths, and N-alkyl groups of the aconite alkaloids are discussed. Pyropseudaconine has been shown to contain a conjugated system. The formulation C19H19–2,(OH)3,(OCH3)4NC2H5has been confirmed for lycoctonine. Study of its oxidation products has shown that lycoctonine has a methylene group adjacent to the nitrogen and a primary hydroxyl group. The two remaining hydroxyls have been shown to be vicinal, with one probably secondary and the other tertiary. A carbinolamine structure is suggested for hydroxylycoctonine. The new bases, isolycoctonine, desoxylycoctonine, and des-(oxymethylene)-lycoctonine are described.This publication has 12 references indexed in Scilit:
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