Cerium aryloxides as precursors for monopentamethylcyclpentadienyl organocerium(III) compounds; X-ray crystal structure of (η5-pentamethylcyclopentadienyl)bis(2,6-di-t-butylphenoxo)cerium
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 962-963
- https://doi.org/10.1039/c39880000962
Abstract
Tris(2,6-di-t-butylphenoxo)cerium reacts with (C5Me5)Li in pentane to form (η5-C5Me5)bis(2,6-di-t-butylphenoxo)cerium, whose structure was established by X-ray crystallography and which, on subsequent reaction with LiCH(SiMe3)2, gives a novel mono(C5Me5)cerium-bisalkyl complex, (C5Me5)Ce[CH(SiMe3)2]2.Keywords
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