Mechanism of photochemical formation of a cyclic nitrone from the nitrite of a fused five-membered ring alcohol
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 376-377
- https://doi.org/10.1039/c39720000376
Abstract
On the basis of the results obtained from a monochromatic light experiment, the photolysis in EPA matrix at 77 K, and the photolysis in solvents such as CCl4, it has been shown that the nitrone (10) is formed in a stereospecific manner by the thermal cyclization of a short-lived intermediate nitroso-aldehyde (5) from a fused cyclopentanol nitrite (2).Keywords
This publication has 0 references indexed in Scilit: