13C And 15N nuclear magnetic resonance parameters of ethyl diazoacetate

1 January 1977

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 11,p. 366-368
https://doi.org/10.1039/c39770000366

Abstract

¹⁵ N Chemical shifts of both singly labelled and the doubly labelled isotopic modifications of ethyl diazoacetate accord with qualitative expectations; the ¹³C–¹⁵N and ¹⁵N–¹⁵N coupling constants compare with calculated values which demonstrate the dominance of the Fermi contact term and the importance of the nitrogen lone pair.

Keywords

NITROGEN
15N
13C
ISOTOPIC
SHIFTS
RESONANCE
DOUBLY
LONE
SINGLY
FERMI