Multiple rhodium(II)–rhodium(III) bond in the dimer [Rh2(O2CMe)4(H2O)2][ClO4]·H2O; X-ray crystal structure
- 1 January 1977
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 760-761
- https://doi.org/10.1039/c39770000760
Abstract
The crystal and molecular structure of tetra-µ-acetatorhodium(II)–rhodium(III) perchlorate has been determined; the complex contains the bimolecular species [Rh2(O2CMe)4(H2O)2]+ with a very short RhII–RhIII distance of 2·3165(20)Å.Keywords
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