Configurational assignment of 2‐alkylsulphinyl‐1‐arylethanol diastereomers by 13C NMR
- 1 August 1988
- journal article
- research article
- Published by Wiley in Magnetic Resonance in Chemistry
- Vol. 26 (8) , 687-692
- https://doi.org/10.1002/mrc.1260260810
Abstract
The relative configurations of erythro‐ and threo‐2‐alkylsulphinyl‐1‐phenyl(or 2‐thiophen or 2‐furyl)ethanol have been correlated with 13C NMR data. A general rule for determining the configuration of this type of compound is presented.Keywords
This publication has 24 references indexed in Scilit:
- Carbon-13 NMR studies of [1-13C]aldoses: empirical rules correlating pyranose ring configuration and conformation with carbon-13 chemical shifts and carbon-13/carbon-13 spin couplingsJournal of the American Chemical Society, 1987
- Application of carbon-13 NMR spectroscopy to acyclic stereochemical analysisThe Journal of Organic Chemistry, 1985
- Carbon-13 nuclear magnetic resonance spectra of trans-1-thiadecalin, trans-1,4-thiadecalin, trans-1,4-oxathiadecalin, and the corresponding sulfoxides and sulfonesThe Journal of Organic Chemistry, 1980
- Carbon-13 nuclear magnetic resonance spectroscopical and stereochemical investigations. 17. Steric effects on carbon-13 nuclear magnetic resonance shifts in alkanesJournal of the American Chemical Society, 1977
- Carbon-13 nuclear magnetic resonance spectroscopical and stereochemical investigations. 18. Electric field effects on carbon-13 nuclear magnetic resonance shifts in heterosubstituted alkanesJournal of the American Chemical Society, 1977
- Structural studies of organosulfur compounds. 3. Stereochemistry and conformational distortions in trans-hexahydro-1,4-benzoxathiane S-oxidesThe Journal of Organic Chemistry, 1977
- Carbon-13 chemical shifts of the pentamethylene heterocyclesJournal of the American Chemical Society, 1976
- Contrasting trends in the C13 shielding effects of neighboring substituents. An aid for stereochemical assignmentsJournal of Magnetic Resonance (1969), 1975
- The stereochemical dependence of δ-substituent effects in 13C NMR spectra. Deshielding syn-axial interactionsJournal of Magnetic Resonance (1969), 1973
- Observations on the n.m.r. spectra of some derivatives of 1,4-oxathian S-oxide. Anisotropy of the S ? O bondChemical Communications (London), 1966