The hydrothermal syntheses and characterization of one- and two-dimensional structures constructed from metal–organic derivatives of polyoxometalates: [{Cu(bpy)2}{Cu(bpy)(H2O)}(Mo5O15){O3P(CH2)4PO3}]·H2O and [{Cu2(tpypyz)(H2O)2}(Mo5O15)(O3PCH2CH2PO3)]·5.5H2O [bpy = 2,2′-bipyridine, tpypyz = tetra(2-pyridyl)pyrazine]
- 3 September 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 1852-1853
- https://doi.org/10.1039/b104860k
Abstract
The hydrothermal reaction of CuSO4·5H2O, Na2MoO4·2H2O and 2,2′-bipyridine with the bridging diphosphonate ligand H2O3P(CH2)4PO3H 2 yields the one-dimensional chain [{Cu(bpy)2}{Cu(bpy)(H2O)2 }(Mo5O15){O3P(CH2) 4PO3}]·H2O; the introduction of a second bridging component in the reaction of Cu(MeCO2)2·H2O, MoO3, H2O3PCH2CH2PO3H 2 and tetra(2-pyridyl)pyrazine yields the network solid [{Cu2(tpypyz)(H2O)2}(Mo5 O15)(O3PCH2CH2PO3 )]·5.5H2O.Keywords
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