Cation-radicals: formation of methoxy-radicals by photochemical and thermal oxidation of methanol
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 16,p. 964-965
- https://doi.org/10.1039/c29710000964
Abstract
Spin-trapping experiments with the nitrone, N-benzylidene-t-butylamine N-oxide (I) and 2-methyl-2-nitrosopropane (IV) have demonstrated that methoxyradicals are important intermediates in photochemical oxidations of methanol by paraquat dichloride, uranyl nitrate, potassium peroxydisulphate, and lead tetraacetate; in the γ-radiolysis of methanol; and in thermal oxidation by potassium peroxydisulphate.Keywords
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