Stereochemistry of the introduction of the hydrogen atom at C-2 of cis-aconitic acid during its transformation into itaconic acid in Aspergillus terreus: a 2H n.m.r. approach
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1050-1051
- https://doi.org/10.1039/c39810001050
Abstract
By 2H n.m.r. spectroscopy it is shown that, during the conversion of cis-aconitic acid (1) into itaconic acid (2), the proton coming from the medium is introduced at C-2 of (1) on the 2-re,3-si face.Keywords
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