Application of the Saegusa Oxidation to Trimethylsilyl Ethers of Diosphenols
- 1 April 1990
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 20 (7) , 989-997
- https://doi.org/10.1080/00397919008052802
Abstract
The Saegusa oxidation of trimethylsilyl ethers of diosphenols provided enediones and served as a key reaction in the conversion of δ2-picrasin B to 1β-hydroxy-12-methoxy-picrasa-3,12-diene-2,11-dione, a model for the A ring functionality of many guassinoids.Keywords
This publication has 10 references indexed in Scilit:
- A partial synthesis of picrasin B and Δ2-picrasin BTetrahedron Letters, 1989
- The Vinylogous Tricarbonyl Chromophore. Violerythrine End Groups and Related Six‐Membered Ring Compounds. Their synthesis, Conformation, and Investigation by Photoelectron, UV, and NMR Spectroscopy and by Crystal Structure Analysis1)European Journal of Inorganic Chemistry, 1987
- New synthetic reactions of allyl alkyl carbonates, allyl .beta.-keto carboxylates, and allyl vinylic carbonates catalyzed by palladium complexesAccounts of Chemical Research, 1987
- Advances in the chemistry of 2,3-epoxyalcohols. New methodology for contra-trans-diaxial opening and selective enediol oxidationThe Journal of Organic Chemistry, 1985
- 4-Benzoyl-4-methylcyclohexa-2,5-dienone and its benzoyl substituted derivatives: isolated 4-acylcyclohexa-2,5-dienonesJournal of the Chemical Society, Chemical Communications, 1985
- Soularubinone, A New Antileukemic Quassinoid From Soulamea tomentosaJournal of Natural Products, 1981
- Synthesis of .alpha.,.beta.-unsaturated carbonyl compounds by palladium(II)-catalyzed dehydrosilylation of silyl enol ethersThe Journal of Organic Chemistry, 1978
- Oxidation of sterically hindered alcohols to carbonyls with dimethyl sulfoxide-trifluoracetic anhydrideThe Journal of Organic Chemistry, 1976
- Tumor inhibitors. 101. Dehydroailanthinone, a new antileukemic quassinoid from Pierreodendron kerstingiiThe Journal of Organic Chemistry, 1975
- The Reaction of Lithium Aluminum Hybride with Alcohols. Lithium Tri-t-butoxyaluminohydride as a New Selective Reducing Agent1,2Journal of the American Chemical Society, 1958