Synthesis of carbocyclic analogues ofD-glucosamine andL-idosamine fromD-flucosamine
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1399-1401
- https://doi.org/10.1039/c39860001399
Abstract
Derivatives of pseudo-D-glucosamine and pseudo-L-idosamine have been prepared from the chiral cyclohexanone (1) by a short sequence, including methoxy-methylenation or methylenation, followed by stereoselective oxymercuration or hydroboration, respectively of the resulting vinyl ether (2) and exocyclic methylene (3).Keywords
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