A Convenient Preparation of Trimethylborane and Triethylborane
- 1 January 1973
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 3 (4) , 359-367
- https://doi.org/10.1080/00945717308057281
Abstract
A convenient, high yield preparation of Me3B on a laboratory scale from (n-BuO)3B and Me3Al2Cl3 is described. The preparation of Et3B from Al3Et and Et2O[sbnd]BF3 on a laboratory scale and from AlEt3 and KBF4 on a pilot plant scale are also given.Keywords
This publication has 8 references indexed in Scilit:
- Diäthylborylierungen und Wasserbestimmungen mit „aktiviertem”︁ TriäthylboranAngewandte Chemie, 1971
- Contributions to the Chemistry of Boron, LVII: The Preparation of Ethyl Haloboranes via the Aluminum Alkyl RouteSynthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 1971
- TRIMETHYLBORONOrganic Preparations and Procedures, 1969
- Aluminum Carbide as a Route to Organoboron and Organoaluminum CompoundsJournal of the American Chemical Society, 1963
- Borverbindungen, I. Darstellung von Bortrialkylen und ihre Reaktionen mit OlefinenEuropean Journal of Organic Chemistry, 1958
- Studies in Stereochemistry. V. The Effect of F-Strain on the Relative Base Strengths of Ammonia and Trimethylamine1Journal of the American Chemical Society, 1945
- Zur Kenntnis des Bormethyls und BoräthylsBerichte der deutschen chemischen Gesellschaft (A and B Series), 1921
- Ueber eine neue Reihe organischer Verbindungen, welche Bor enthaltenEuropean Journal of Organic Chemistry, 1862