Binding properties and crystal structure of a hemicarcerand containing four diethylene glycol units connecting two bowls
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1825-1827
- https://doi.org/10.1039/c39950001825
Abstract
A hemicarcerand composed of two bowls attached at their rims with four O(CH2CH2O)2 units, when heated with 22 guests containing 6–12 rigidly-arranged non-hydrogen atoms, formed 22 isolable, characterized hemicarceplexes, but failed to form isolable complexes with 34 other potential guests of the same molecular size range.Keywords
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