Migration of Silicon from Oxygen to Carbon in O-Trialkylsilyl Ketene Acetals
- 1 April 1987
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 17 (6) , 637-646
- https://doi.org/10.1080/00397918708075737
Abstract
The migration of silicon from oxygen to carbon for 1 and 3 is intramolecular. The half—life of migration is not influenced by the presence of t-BuMe2SiCI or triethyIbenzylammonium chloride.Keywords
This publication has 10 references indexed in Scilit:
- Organometallic high pressure reaction. 5. A new procedure for the synthesis of .alpha.-silylated esters and lactones. Migration of silicon from oxygen to carbon at high pressureOrganometallics, 1984
- .alpha.-Silylation of lithium ester enolatesJournal of the American Chemical Society, 1981
- Interconversion of .gamma.-silyl .alpha.,.beta.-unsaturated carbonyl compounds and siloxybutadienes by 1,5-shifts of silicon between carbon and oxygenThe Journal of Organic Chemistry, 1981
- Reaction of lithium N,N-dialkylamide enolates with trialkylchlorosilanesThe Journal of Organic Chemistry, 1978
- The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formationJournal of the American Chemical Society, 1976
- Molecular rearrangements of organosilicon compoundsAccounts of Chemical Research, 1974
- O-Silylation and Attempted O-Alkylation of Lithium Ester Enolates. The Synthesis of O-Silyl Ketene AcetalsSynthetic Communications, 1973
- Ketene alkyltrialkylsilyl acetals: synthesis, pyrolysis and NMR studiesJournal of Organometallic Chemistry, 1972
- Stereochemistry of the formation and thermalrearrangement of .beta.-ketosilanesJournal of the American Chemical Society, 1967
- The synthesis and the rearrangement of O-silyl-O-alkyl keteneacetals into esters of silylacetic acidJournal of Organometallic Chemistry, 1966