[MeO(CH2CH2O)3(CH2)3C5Me4]FeCl: A Halfsandwich Iron (II) Chloride Complex of Remarkable Stability
- 1 November 1995
- journal article
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 128 (11) , 1135-1136
- https://doi.org/10.1002/cber.19951281113
Abstract
Reaction of iron(II) chloride with one equivalent of [MeO‐(CH2CH2O)3(CH2)3C5Me4]Li in THF yields the title halfsand‐wich complex 1, which is stable in solution up to room temperature. Compound 1 reacts with C5H5Li and CO to give [MeO(CH2CH2O)3(CH2)3C5Me4]Fe(C5H5) (2) and [MeO‐(CH2CH2O)3(CH2)3C5Me4]Fe(CO)2CI (3), respectively, in high yields.Keywords
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