Control of product selectivity for the epoxidation of allyl alcohol by variation of the acidity of the catalyst TS-1
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 1095-1096
- https://doi.org/10.1039/c39940001095
Abstract
The acidity of TS-1 controls the product selectivity for the epoxidation of allyl alcohol with H2O2; base treatment of TS-1 enhances the selectivity to glycidol whereas incorporation of Brønsted acid sites enhances the selectivity to the products of solvolysis ring opening reactions.Keywords
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