Hydrogen bonding and cooperativity effects on the assembly of carbohydrates
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 4,p. 465-466
- https://doi.org/10.1039/a708386f
Abstract
The effect of intramolecular hydrogen bonds on the cooperative assembly of carbohydrate derivatives has been evaluated; the 1,3-diaxial OH···OH intramolecular hydrogen bond is at the origin of the dimerization of diol 1; and one intermolecular OH···OH bond accounts for 2.5 kcal mol– 1 in CDCl3 and 3 kcal mol–1 in CDCl3–CCl4.Keywords
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