Quenching of triplet states of aromatic hydrocarbons by quinones due to favourable charge-transfer interactions. Part 2.—Solvent effects
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 75, 896-904
- https://doi.org/10.1039/f29797500896
Abstract
Rate constants for quenching of the triplet states of 1,2-benzanthracene and/or anthracene by 2,5-dimethyl-p-benzoquinone, 2-methyl-p-benzoquinone and p-benzoquinone have been measured in eight different solvents at room temperature. For those solvents with low dielectric constants, (< 10), i.e., toluene, cyclohexane, ethyl acetate and tetrahydrofuran, rate constants for quenching kQ, relative to those for diffusion controlled reactions kd, have been shown to depend on ΔGCT, the free energy change expected for charge transfer to give a dielectrically non-relaxed CT state, in the same manner and to show the same correlation between log (kQ/kd) and ΔGCT as found previously in similar studies for benzene as solvent. Quenching is relatively more efficient in polar solvents (acetonitrile, N,N-dimethyl-formamide and formamide) when ΔGCT > –0.1 eV but again there is no correlation with static dielectric constant or with solvent reorientation energies, and it is suggested that quenching may result in these solvents from only partial charge transfer.Keywords
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