Synthesis of ?-Ketoamine Derivatives of Aluminum
- 1 January 1971
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 1 (4) , 287-294
- https://doi.org/10.1080/00945717108057273
Abstract
Aluminium isopropoxide reacts with β-ketoamines (CH3C(O)CHC(NHR)CH3, R = ethyl, n-propyl, n-butyl) in benzene to give the mono-, bis-, and tris- ketoamine complexes of aluminium (depending on the ratio of reactants) in a clean, high-yield reaction. The hydrolytically unstable products are relatively volatile, soluble and monomeric in benzene. The infrared spectra of the complexes are reported.Keywords
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