Synthesis and single-crystal x-ray structural investigation of 1,1-bis(pentacarbonylmanganio)-3,4-dimethylgermacyclopent-3-ene and bis[1-(tetracarbonylferrio)-3,4-dimethylgermacyclopent-3-ene]: the first evidence for a puckered ground-state conformation in germacyclopent-3-enes

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