A new series of radical-cation salts based on asymmetrical ethylenedithiodimethyl-tetrathiafulvalene (EDTDM-TTF). Properties and crystal structure of (EDTDM-TTF)2PF6

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Abstract
A new series of radical-cation salts with inorganic anions PF6–, Br–, ClO4–, HgCl3 –, I– has been prepared by electrochemical oxidation of ethylenedithiodimethyltetrathiafulvalene (EDTDM-TTF); the electrical conductivity and crystal structure of one of them, (EDTDM-TTF)2PF6, are reported and the three-dimensional character of its arrangement is suggested.