Remarkable axial ligand effect on regioselectivity towards terminal alkenes in epoxidation of dienes by a robust manganese porphyrin
- 28 January 2003
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 5,p. 620-621
- https://doi.org/10.1039/b210645k
Abstract
With a highly encumbered manganese porphyrin as catalyst, significant improvements in regioselectivity towards less substituted C–C double bond in diene epoxidation were attained by simply adding organic bases as axial ligand.Keywords
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