Synthetic Usefulness of the Cobalt(I)-Mediated Ene Type Reaction for the Diastereoselective Construction of Bicyclo[n.3.0]derivatives
- 1 August 1997
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1997 (8) , 931-932
- https://doi.org/10.1055/s-1997-943
Abstract
Cobalt(I)-catalyzed cycloisomerization of cyclic ℇ-acetylenic β-ketoesters 1 led to bicyclo[n.3.0]derivatives 2 in high yield and with a total stereocontrol of two contiguous centers.Keywords
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