Group IVB dicyanoethylene-1,2-dithiolato-complexes
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 500-503
- https://doi.org/10.1039/j19710000500
Abstract
The reactions between disodium dicyanoethylene-1,2-dithiolate (Na2mnt) and various Group IVB halides and acetates have been investigated. Complexes exhibiting the following stoicheiometries have been prepared and characterized: M(mnt)3 2–(M = Sn or Ge), Sn(mnt)2X2 2–(X = Cl, Br, or I), Pb(mnt)2 2–, and Pb(mnt)Br–. X-Ray powder patterns, conductivity data, i.r. spectra and electronic spectra are reported and discussed.Keywords
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