Model-potential calculations for Σ, Π, Δ excited states of Na2+and K2+: energies, dipole moment and radial coupling
- 14 August 1985
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic and Molecular Physics
- Vol. 18 (15) , 3085-3103
- https://doi.org/10.1088/0022-3700/18/15/015
Abstract
A model-potential method including core polarisation effects is used to obtain the Sigma , Pi , Delta states of Na2+ and K2+, up to the states dissociating to the 6s atomic state. Dipole moments and radial coupling matrix elements are calculated. The structure of the energy curves is analysed in terms of molecular quantum defects.Keywords
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