An Experimental Technique for Studying the Infrared Spectrum of Chemisorbed Compounds

Abstract
Two specially designed infrared cells are described for use in studying chemisorption gas-solid reactions. The gas phase spectrum of diisopropyl methyl phosphonate and dimethyl methyl phosphonate both before and after reaction with a transition metal solid, FeCl3, are shown, using these new cells. Assignments are made for all bands in the spectrum of these compounds.

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