N.m.r. spectra of silicon hydride derivatives. Part 6.—Group 5 trisilyls
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 62, 3282-3286
- https://doi.org/10.1039/tf9666203282
Abstract
The proton magnetic resonance spectra of the group 5 trisilyls are reported, including the satellite spectra due to 29Si at natural abundance. A double resonance experiment shows that the two 29SiH coupling constants in P(SiH3)3 have the same sign. The phosphorus spectrum of the latter is described, and J(29SiP) tentatively assigned.Keywords
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