A simple single-step synthesis of [99Tc3H3(CO)12] from [99TcO4]–and its X-ray crystal structure. Application to the production of no-carrier added [188Re3H3(CO)12]
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 1291-1292
- https://doi.org/10.1039/cc9960001291
Abstract
Reduction of no-carrier added [188ReO4]–(ng range) in thf–[NBu4]Cl with BH3·thf under an atmosphere of CO yields [188ReCl3(CO)3]2– and [188Re3(µ-H)3(CO)12]; under similar conditions as with [188ReO4]–, the first µ-hydrido-bridged 99Tc hydrido carbonyl complex is prepared and structurally characterised.Keywords
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